Through the ages the alchemists
claimed that they could change one metal into another, particularly base metals
into gold. One possibility was to change lead into gold but any gold found after
the reaction probably came from the spectacle frames of the
experimenters!
However in 1919 an experiment was performed that
actually did change one material into another – although not into gold – when
alpha particles colliding with nitrogen nuclei were found to give off protons.
Two reactions are possible:
  | 147N | + | 42He | gives | 136C | + | 11H | + | 42He |   | or |
  | 147N | + | 42He | gives | 178O | + | 11H |
By studying the tracks of the particles emitted in the reaction in a cloud chamber it was shown that it was the second reaction that had occurred: the alpha particles had actually been absorbed by the nucleus and had not simply 'chipped off' a proton.
A simplified diagram of the apparatus is
shown above.
The alpha source produced a reaction in the gas and the
resulting protons were detected using a zinc sulphide screen. With heavy
elements alpha particle scattering occurs instead.
1 mg of radium emits
about 37 000 000 alpha particles per second but even this enormous number
does not cause many interactions because of the 'large' spaces between the
nuclei. It required the development of particle accelerators before sufficiently high
particle densities could be obtained. In 1932, using a 400 000 V accelerator,
Cockcroft, Walton and Rutherford succeeded in transmuting a nucleus of lithium
into two helium nuclei.
  | 73Li | + | 11H | gives | 242He |